Verdigris
The green corrosion product on copper and brass. On a roof it is protective; on a tap, a pan or a fitting it is a symptom of trapped moisture.
In detail
Verdigris is the green or blue-green layer that forms on copper and copper alloys as they corrode, chemically a mixture of basic copper carbonates, sulphates or chlorides depending on what the metal has been exposed to. It is not dirt and it is not tarnish in the sense that silver tarnishes: it is the metal itself converted into a new compound, so removing it removes material. On architectural copper the layer is stable, adherent and protective, which is why a church roof is left alone. On plumbing fittings, cookware, instrument keys and decorative brass it means something different — moisture is being trapped against the metal, usually by a cloth left in contact, a damp cupboard, or a cleaning product that was not rinsed and dried off. The carpet institute's copper corrosion and brass stain entries are about the marks such fittings leave on a textile rather than about the metal, and both are short: detergent solution, warm water, professional. On the metal itself the trade guidance for copper alloys is that treatment must be matched to whether the piece is lacquered, patinated deliberately, or bare, because a polish appropriate to one destroys another.
What works
Non-ionic detergent is effective against Verdigris Established practitioner practice
Why
- Verdigris is explained by Corrosion and passivation
Hacks and claims involving this
- Lemon and salt to clean copper Established practitioner practice
Sources for this page
Sources
Technical Procedures: Cleaning of Copper Alloy Objects
United States General Services Administration (GSA), Historic Preservation · Reference work
Relied on for: That copper alloys form corrosion layers whose treatment depends on whether the surface is bare, lacquered or deliberately patinated. (states this directly)
Verification: a person has read the passage relied on.
Read on — Section 2.02, cleaning of copper alloy objects, and 2.03, application of clear coat. Supports the claim as stated.
Spot Solver: spot and spill removal procedures
The Carpet and Rug Institute (CRI) · Trade or professional body
Relied on for: That the copper corrosion and brass stain entries route to a detergent solution, warm water and then a professional. (states this directly)
Verification: a person has read the passage relied on.
Read on — Sprint 5-10: fifteen entries, stain by stain. Sprint 30: enumerated at 296 from the publisher's own sitemap, 134 more read plus 'Unknown'. Sprint 38: 56 more, chosen against stains the catalogue lacked. 192 of 296 read. Supports the claim as stated.
Last reviewed by a person on .