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Verdigris

The green corrosion product on copper and brass. On a roof it is protective; on a tap, a pan or a fitting it is a symptom of trapped moisture.

In detail

Verdigris is the green or blue-green layer that forms on copper and copper alloys as they corrode, chemically a mixture of basic copper carbonates, sulphates or chlorides depending on what the metal has been exposed to. It is not dirt and it is not tarnish in the sense that silver tarnishes: it is the metal itself converted into a new compound, so removing it removes material. On architectural copper the layer is stable, adherent and protective, which is why a church roof is left alone. On plumbing fittings, cookware, instrument keys and decorative brass it means something different — moisture is being trapped against the metal, usually by a cloth left in contact, a damp cupboard, or a cleaning product that was not rinsed and dried off. The carpet institute's copper corrosion and brass stain entries are about the marks such fittings leave on a textile rather than about the metal, and both are short: detergent solution, warm water, professional. On the metal itself the trade guidance for copper alloys is that treatment must be matched to whether the piece is lacquered, patinated deliberately, or bare, because a polish appropriate to one destroys another.

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Sources for this page

Sources

  1. Technical Procedures: Cleaning of Copper Alloy Objects

    United States General Services Administration (GSA), Historic Preservation · Reference work

    Relied on for: That copper alloys form corrosion layers whose treatment depends on whether the surface is bare, lacquered or deliberately patinated. (states this directly)

    Verification: a person has read the passage relied on.

    Read on Section 2.02, cleaning of copper alloy objects, and 2.03, application of clear coat. Supports the claim as stated.

  2. Spot Solver: spot and spill removal procedures

    The Carpet and Rug Institute (CRI) · Trade or professional body

    Relied on for: That the copper corrosion and brass stain entries route to a detergent solution, warm water and then a professional. (states this directly)

    Verification: a person has read the passage relied on.

    Read on Sprint 5-10: fifteen entries, stain by stain. Sprint 30: enumerated at 296 from the publisher's own sitemap, 134 more read plus 'Unknown'. Sprint 38: 56 more, chosen against stains the catalogue lacked. 192 of 296 read. Supports the claim as stated.

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