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Linear alkylbenzene sulphonate

The workhorse anionic surfactant behind most washing-up liquids and laundry powders — the specific molecule the word 'detergent' usually stands in for.

Precautions

  • Never mix with other cleaning products
  • Rinse thoroughly afterwards

In detail

Most of what this catalogue says about surfactants is said in general terms, and this record exists so that at least one of them is a named compound with a regulator behind it. Linear alkylbenzene sulphonate is the anionic surfactant that dominates domestic cleaning products by volume: a long hydrocarbon tail that buries itself in oil, and a sulphonate head that stays in the water. The New Jersey Department of Health describes it as a white to light yellow sand-like solid used as a detergent, in cleaning products and in pesticides. Its reactivity list is short and useful — incompatible with oxidising agents including chlorine, and with strong acids. That is the regulator-sourced half of the question readers ask as 'can I mix bleach and washing-up liquid', and it is deliberately only half. The sheet describes the pure compound; a bottle of washing-up liquid is a formulation containing several surfactants, salts, preservatives and perfumes, and what it does when poured into bleach is a question about that formulation rather than about this molecule. CleaningHQ has not raised its position on that mixing question on the strength of this reading, and says so.

Properties

Chemical name
Sodium dodecylbenzene sulphonate
pH
Varies by product

What works

Why

Sources for this page

Sources

  1. Right to Know Hazardous Substance Fact Sheet: Sodium Dodecylbenzene Sulfonate (RTK 1698)

    New Jersey Department of Health, 2002 · Government or regulator

    Relied on for: That sodium dodecylbenzene sulphonate is used as a detergent and in cleaning products, and that it is incompatible with oxidising agents including chlorine and with strong acids. (states this directly)

    Verification: a person has read the passage relied on.

    Read on The 'IDENTIFICATION' paragraph and the 'HANDLING AND STORAGE' reactivity list. Supports a narrower statement — our claim was reduced. Recorded as supporting a narrower statement than the question it bears on. It establishes that the workhorse anionic surfactant is incompatible with chlorine and strong acids as a substance; it does NOT establish what a specific bottle of washing-up liquid does when poured into bleach, because a formulated product contains more than one ingredient. The existing bleach-plus-detergent claim was left at its previous support level rather than raised on this reading.

Last reviewed by a person on .

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