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Linear alkylbenzene sulphonate

The workhorse anionic surfactant behind most washing-up liquids and laundry powders — the specific molecule the word 'detergent' usually stands in for.

Precautions

  • Never mix with other cleaning products
  • Rinse thoroughly afterwards

In detail

Surfactants are usually described in general terms; this is one named compound with a regulator behind its identity. Linear alkylbenzene sulphonate is the anionic surfactant that dominates domestic cleaning products by volume: a long hydrocarbon tail that buries itself in oil, and a sulphonate head that stays in the water. The New Jersey Department of Health describes it as a white to light yellow sand-like solid used as a detergent, in cleaning products and in pesticides. Its reactivity list is short and useful — incompatible with oxidising agents including chlorine, and with strong acids. That answers only half of the question readers ask as 'can I mix bleach and washing-up liquid', and only the regulator-sourced half. The sheet describes the pure compound; a bottle of washing-up liquid is a formulation containing several surfactants, salts, preservatives and perfumes, and what it does when poured into bleach is a question about that formulation rather than about this molecule. No authoritative source addresses what a finished washing-up liquid does when it meets bleach, so the rule against mixing products stands unchanged.

Properties

Chemical name
Sodium dodecylbenzene sulphonate
pH
Varies by product

What works

Why

Sources for this page

Sources

  1. Right to Know Hazardous Substance Fact Sheet: Sodium Dodecylbenzene Sulfonate (RTK 1698)

    New Jersey Department of Health, 2002 · Government or regulator

    Relied on for: That sodium dodecylbenzene sulphonate is used as a detergent and in cleaning products, and that it is incompatible with oxidising agents including chlorine and with strong acids. (states this directly)

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