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Why old stains are harder

Time is not neutral. A stain that has sat is chemically a different problem from the one that was spilled, and four separate processes are responsible.

In detail

Every trade procedure this catalogue has read opens with some version of act quickly, and the reason is not urgency for its own sake. Four things happen to a deposit over time and each makes it harder. It PENETRATES, moving from the surface into the structure by capillary action, so a mark that could have been blotted becomes one that has to be extracted. It DRIES, which concentrates whatever was dissolved in it and brings the deposit into intimate contact with the substrate. It OXIDISES, and this is the one that changes the chemistry outright — many pigments and oils react with atmospheric oxygen into new, more strongly coloured and less soluble compounds, which is why an old oil mark yellows and why a stain nobody could see reappears brown months later. And in the case of sugars and some proteins it POLYMERISES or cross-links, becoming a solid film rather than a residue. The consequence is that the treatment which would have worked on day one may not simply be less effective later; it may be the wrong treatment for what is now there. The conservation guidance names brown oxidised stains as a category of their own, separate from greasy soiling and general grime.

Why

Sources for this page

Sources

  1. Spot Solver: spot and spill removal procedures

    The Carpet and Rug Institute (CRI) · Trade or professional body

    Relied on for: That delaying may cause a spill to become a permanent stain, and that acting quickly is the opening instruction of every procedure in the database. (states this directly)

    Verification: a person has read the passage relied on.

    Read on Sprint 5-10: fifteen entries, stain by stain. Sprint 30: enumerated at 296 from the publisher's own sitemap, 134 more read plus 'Unknown'. Sprint 38: 56 more, chosen against stains the catalogue lacked. 192 of 296 read. Supports the claim as stated.

  2. Conserve O Gram 16/2: Dry Cleaning Museum Textiles

    National Park Service, US Department of the Interior · Government or regulator

    Relied on for: That brown oxidised stains and overall yellow or brown discolouration are assessed as distinct categories from greasy spots and generalised grimy soiling. (states this directly)

    Verification: a person has read the passage relied on.

    Read on The section headed Examination and Assessment, including the soiling checklist. Supports the claim as stated. Gives the solvent-treatment method an authority on WHEN it is the right branch, expressed as soil type rather than as fabric type, which is the distinction the catalogue already draws elsewhere.

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