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Potassium hydroxide

The other caustic alkali, and the one a regulator puts a number to: liquid drain cleaners contain a quarter to a third of it by weight.

What not to do

Potassium hydroxide is unsafe on Aluminium

Unsafe

Do not do this. The risk is established, and it is described below.

The reaction gives off hydrogen, which is flammable. This is a hazard as well as a damage warning.

Precautions

  • Ventilate the area
  • Wear gloves
  • Wear eye protection

Evidence

Strongly supported

Sources

  1. Right to Know Hazardous Substance Fact Sheet: Potassium Hydroxide (RTK 1571)

    New Jersey Department of Health, 2010 · Government or regulator

    Relied on for: That potassium hydroxide is corrosive in moist air to aluminium, zinc, tin and lead and forms flammable and explosive hydrogen gas. (states this directly)

Potassium hydroxide is unsafe on Galvanised steel

Unsafe

Do not do this. The risk is established, and it is described below.

Precautions

  • Wear gloves
  • Wear eye protection

Evidence

Strongly supported

Sources

  1. Right to Know Hazardous Substance Fact Sheet: Potassium Hydroxide (RTK 1571)

    New Jersey Department of Health, 2010 · Government or regulator

    Relied on for: That potassium hydroxide is corrosive in moist air to metals including zinc. (states this directly)

Potassium hydroxide is unsafe on Natural rubber

Unsafe

Do not do this. The risk is established, and it is described below.

Evidence

Supported

Sources

  1. Right to Know Hazardous Substance Fact Sheet: Potassium Hydroxide (RTK 1571)

    New Jersey Department of Health, 2010 · Government or regulator

    Relied on for: That potassium hydroxide attacks some forms of plastics, rubber and coatings. (states this directly)

Precautions

  • Never mix with other cleaning products
  • Wear gloves
  • Wear eye protection
  • Ventilate the area
  • Keep away from children and pets
  • Rinse thoroughly afterwards

In detail

Potassium hydroxide is sodium hydroxide's twin, and domestic products are formulated on whichever is cheaper or more soluble for the job. The New Jersey fact sheet does something its sodium counterpart does not — it says how much is in the bottle: liquid drain cleaners contain 25 to 36 per cent potassium hydroxide. That figure is worth having, because it turns a category statement about caustics into something a reader can weigh against what the same sheet says happens on contact, which is that this is a highly corrosive chemical whose contact can severely irritate and burn skin and eyes leading to eye damage. On surfaces the decisive fact is a metals one. Potassium hydroxide is corrosive in moist air to aluminium, zinc, tin and lead, forming flammable and explosive hydrogen gas as it goes. Aluminium is the one that matters domestically, because it turns up as bakeware, pan bases, extractor trim and window frames, and a caustic oven or drain product that touches any of them does visible, permanent damage. It also attacks some plastics, rubbers and coatings, and reacts violently with strong acids.

Properties

Chemical name
Potassium hydroxide
pH
Strongly alkaline

What works

  • Potassium hydroxide is effective against Grease Supported

    It converts fat into soap rather than lifting it, which is why it works where a detergent has already failed.

Why

Sources for this page

Sources

  1. Right to Know Hazardous Substance Fact Sheet: Potassium Hydroxide (RTK 1571)

    New Jersey Department of Health, 2010 · Government or regulator

    Relied on for: That liquid drain cleaners contain 25 to 36 per cent potassium hydroxide, that it is highly corrosive, and that it is corrosive in moist air to aluminium, zinc, tin and lead, forming hydrogen gas. (states this directly)

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