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Polished marble

A calcium carbonate stone with a polished finish. Chemically attacked by acids, including household ones, and the damage is permanent.

What not to do

Acetic acid (vinegar) is unsafe on Polished marble

Unsafe

Do not do this. The risk is established, and it is described below.

Etching is chemical removal of the stone, not a stain. It cannot be cleaned off and the surface has to be re-polished.

Precautions

  • Test on an inconspicuous area first

Why we say this

Strongly supported

The stone trade states the prohibition directly and the chemistry is uncontested. Re-pointed in Sprint 2 from the association's unread design manual to its consumer guidance, which was read.

Sources

  1. Care & Cleaning of Natural Stone

    Natural Stone Institute · Trade or professional body

    Relied on for: That products containing lemon, vinegar or other acids may dull or etch calcareous stones, and that calcareous stone is sensitive to acidic solutions. (states this directly)

    Verification: a person has read the passage relied on.

    Read on Sprint 29 read all nine sections. Earlier sprints had read three: the siliceous-versus-calcareous classification, cleaning products, and sealing. Supports a wider statement — our claim was widened. Three sections of nine had been read and the source treated as complete. The unread six carry the whole preventive programme - coasters, trivets, non-treated dry mopping, slip-resistant mats, worn vacuum wheels, blot-don't-wipe - none of which the register held. They also answer a priority-1 row reading 'no route answers this yet': the authority's position on etch marks is that they are not a cleaning problem and need professional re-polishing. Two oddities are worth the record: dry 0000 steel wool is permitted on water rings, and efflorescence is removed dry because water makes it worse.

  2. Kirk-Othmer Encyclopedia of Chemical Technology

    John Wiley & Sons · Reference work

    Relied on for: That acids react with calcium carbonate to form soluble salts. (background and mechanism only)

    Verification: the work exists and is described correctly. Nobody has yet read the specific passage.

Last reviewed by a person on .

Citric acid is unsafe on Polished marble

Unsafe

Do not do this. The risk is established, and it is described below.

Precautions

  • Test on an inconspicuous area first

Why we say this

Strongly supported

The prohibition is stated for acids as a class rather than for vinegar specifically, so it reaches citric acid and every commercial descaler built on it.

Sources

  1. Care & Cleaning of Natural Stone

    Natural Stone Institute · Trade or professional body

    Relied on for: That calcareous stone is sensitive to acidic solutions and that acids may dull or etch it. (states this directly)

    Verification: a person has read the passage relied on.

    Read on Sprint 29 read all nine sections. Earlier sprints had read three: the siliceous-versus-calcareous classification, cleaning products, and sealing. Supports a wider statement — our claim was widened. Three sections of nine had been read and the source treated as complete. The unread six carry the whole preventive programme - coasters, trivets, non-treated dry mopping, slip-resistant mats, worn vacuum wheels, blot-don't-wipe - none of which the register held. They also answer a priority-1 row reading 'no route answers this yet': the authority's position on etch marks is that they are not a cleaning problem and need professional re-polishing. Two oddities are worth the record: dry 0000 steel wool is permitted on water rings, and efflorescence is removed dry because water makes it worse.

  2. Kirk-Othmer Encyclopedia of Chemical Technology

    John Wiley & Sons · Reference work

    Relied on for: That acids react with calcium carbonate to form soluble salts. (background and mechanism only)

    Verification: the work exists and is described correctly. Nobody has yet read the specific passage.

Last reviewed by a person on .

Precautions

  • Test on an inconspicuous area first

In detail

Marble is a metamorphic rock composed mainly of calcium carbonate. That single fact governs almost everything about cleaning it. Calcium carbonate reacts with acids, so any acidic cleaner — vinegar, lemon juice, citric acid descaler, many limescale and bathroom products — attacks the stone itself rather than only what is sitting on it. The result is etching: a dull, slightly rough mark where the polished surface has been chemically removed. Etching is not a stain and cannot be cleaned off, because there is nothing on the surface to remove. Restoring it means re-polishing the stone. The stone trade draws this distinction explicitly, noting that some substances etch without staining and others do both — which matters because the two need opposite responses, and treating an etch mark as a stain leads to progressively harsher cleaning of a surface that has nothing on it. Marble is also porous enough to absorb oils and pigments, which is why spills are a timing problem as much as a chemistry one. Impregnating treatments reduce absorption; they do not make the stone acid-resistant, and a treated marble worktop etches just as readily as an untreated one.

Properties

Sensitivity

Acids
Recorded
Alkalis
Not known
Chlorine bleach
Not known
Heat
Not known
Abrasion
Recorded
Porous
Recorded

“Not known” means CleaningHQ has not established this, not that the material is unaffected.

What works

    Neutral cleaner is safe on, in specific conditions, Polished marble

    Safe only in specific conditions

    This is only appropriate within specific limits. Outside those limits, CleaningHQ makes no claim.

    Only within these limits:

    • A neutral cleaner, stone soap, or mild washing-up detergent in warm water
    • No acidic or alkaline additive of any kind
    • Test an inconspicuous area first on any stone whose finish is unknown

    The stone trade gives the same recommendation for acid-sensitive and acid-resistant stone alike, which means the compatibility question does not have to be resolved before cleaning.

    Precautions

    • Test on an inconspicuous area first

    Why we say this

    Supported

    The only positive clearance for marble in the catalogue, and it rests on the stone trade association's own consumer guidance, which was read in full during this sprint.

    Sources

    1. Care & Cleaning of Natural Stone

      Natural Stone Institute · Trade or professional body

      Relied on for: That stone surfaces are cleaned with a neutral cleaner, stone soap, or a mild liquid dishwashing detergent and warm water. (states this directly)

      Verification: a person has read the passage relied on.

      Read on Sprint 29 read all nine sections. Earlier sprints had read three: the siliceous-versus-calcareous classification, cleaning products, and sealing. Supports a wider statement — our claim was widened. Three sections of nine had been read and the source treated as complete. The unread six carry the whole preventive programme - coasters, trivets, non-treated dry mopping, slip-resistant mats, worn vacuum wheels, blot-don't-wipe - none of which the register held. They also answer a priority-1 row reading 'no route answers this yet': the authority's position on etch marks is that they are not a cleaning problem and need professional re-polishing. Two oddities are worth the record: dry 0000 steel wool is permitted on water rings, and efflorescence is removed dry because water makes it worse.

    Last reviewed by a person on .

    Blotting is appropriate for Polished marble

    Safe in the conditions described

    Authoritative guidance supports this combination, within the conditions described below.

    Sprint 29. From the preventive section nobody had opened.

    Only within these limits:

    • Immediately, with a paper towel
    • Blot rather than wipe — wiping spreads the spill
    • Followed by the routine neutral-cleaner wash where a mark remains

    The instruction is one sentence and it is the whole of the emergency response the authority gives for a spill on stone.

    Why we say this

    Supported

    Stated directly by the stone trade body in its own care guidance, and cleared rather than made conditional because blotting a spill carries no risk the source qualifies.

    Sources

    1. Care & Cleaning of Natural Stone

      Natural Stone Institute · Trade or professional body

      Relied on for: That a spill on natural stone is blotted with a paper towel immediately and the area is not wiped, because wiping will spread the spill. (states this directly)

      Verification: a person has read the passage relied on.

      Read on Sprint 29 read all nine sections. Earlier sprints had read three: the siliceous-versus-calcareous classification, cleaning products, and sealing. Supports a wider statement — our claim was widened. Three sections of nine had been read and the source treated as complete. The unread six carry the whole preventive programme - coasters, trivets, non-treated dry mopping, slip-resistant mats, worn vacuum wheels, blot-don't-wipe - none of which the register held. They also answer a priority-1 row reading 'no route answers this yet': the authority's position on etch marks is that they are not a cleaning problem and need professional re-polishing. Two oddities are worth the record: dry 0000 steel wool is permitted on water rings, and efflorescence is removed dry because water makes it worse.

    Last reviewed by a person on .

    Dry soil removal is appropriate for Polished marble

    Safe in the conditions described

    Authoritative guidance supports this combination, within the conditions described below.

    Sprint 29. Grit is the abrasive, and the preventive section is where the register was blind.

    Only within these limits:

    • A CLEAN, NON-TREATED, DRY dust mop — a treated mop is not what is cleared
    • Frequently, because the control is removing grit before it is walked in
    • Mats and rugs with slip-resistant backing to reduce what arrives
    • Vacuum attachments and wheels checked for wear, which scratch when worn

    The trade body's preventive programme is that what damages a stone floor is abrasive grit carried onto it, and that frequent dry removal is the control rather than more washing.

    Precautions

    • Test on an inconspicuous area first

    Why we say this

    Supported

    The trade body's preventive programme is explicit that what damages stone floors is abrasive grit carried onto them, and that frequent dry removal is the control. The non-treated qualifier on the mop and the worn-wheel caution are both specific enough to be worth carrying rather than summarising.

    Sources

    1. Care & Cleaning of Natural Stone

      Natural Stone Institute · Trade or professional body

      Relied on for: That interior stone floors are dust-mopped frequently with a clean, non-treated dry dust mop, that mats and rugs with slip-resistant backing minimise abrasive material reaching the stone, and that a vacuum's worn attachments or wheels may scratch. (states this directly)

      Verification: a person has read the passage relied on.

      Read on Sprint 29 read all nine sections. Earlier sprints had read three: the siliceous-versus-calcareous classification, cleaning products, and sealing. Supports a wider statement — our claim was widened. Three sections of nine had been read and the source treated as complete. The unread six carry the whole preventive programme - coasters, trivets, non-treated dry mopping, slip-resistant mats, worn vacuum wheels, blot-don't-wipe - none of which the register held. They also answer a priority-1 row reading 'no route answers this yet': the authority's position on etch marks is that they are not a cleaning problem and need professional re-polishing. Two oddities are worth the record: dry 0000 steel wool is permitted on water rings, and efflorescence is removed dry because water makes it worse.

    Last reviewed by a person on .

    Where the answer depends

    Controlled resurfacing is appropriate for Polished marble

    Depends on the manufacturer

    This depends on the specific product or finish. Check the manufacturer's own instructions before proceeding.

    Sprint 29. The authority's answer to etching is that it is not a cleaning problem at all.

    Precautions

    • Consider professional help
    • Test on an inconspicuous area first

    Why we say this

    Supported

    The stone trade body names re-polishing by a professional as the response to etching. Recorded as manufacturer- or professional-dependent rather than as a domestic clearance, because the authority's own instruction is to hand it over. That is a real answer to a question the register had recorded as unanswerable, even though it is not a method.

    Sources

    1. Care & Cleaning of Natural Stone

      Natural Stone Institute · Trade or professional body

      Relied on for: That etch marks are addressed by contacting a professional for re-polishing rather than by any cleaning treatment, and that acidic products including lemon and vinegar may dull or etch calcareous stones. (states this directly)

      Verification: a person has read the passage relied on.

      Read on Sprint 29 read all nine sections. Earlier sprints had read three: the siliceous-versus-calcareous classification, cleaning products, and sealing. Supports a wider statement — our claim was widened. Three sections of nine had been read and the source treated as complete. The unread six carry the whole preventive programme - coasters, trivets, non-treated dry mopping, slip-resistant mats, worn vacuum wheels, blot-don't-wipe - none of which the register held. They also answer a priority-1 row reading 'no route answers this yet': the authority's position on etch marks is that they are not a cleaning problem and need professional re-polishing. Two oddities are worth the record: dry 0000 steel wool is permitted on water rings, and efflorescence is removed dry because water makes it worse.

    Last reviewed by a person on .

    Why

    Hacks and claims involving this

    When the obvious answer is wrong

    How do I remove limescale from a marble shower without ruining the marble?

    Marble is also calcium carbonate. The acid cannot distinguish between carbonate deposited by hard water and carbonate that is the stone itself, so it dissolves both. The result on the stone is etching: a dull, slightly rough patch where the polished surface has been chemically removed. It is not a stain and there is nothing left on the surface to clean off.

    A different kind of treatment works: Take the mechanical route rather than the chemical one. The stone trade's stated treatment for surface accumulation of hard water — what it calls water spots and rings — is to buff with dry 0000 steel wool, which is fine enough to lift the mineral film without cutting the stone, and involves no acid at all. Work on the deposit only, keep it dry, and stop as soon as the film has gone. Prevention does more than any treatment here: a squeegee after each use removes the water before it can evaporate and leave its minerals behind, which is the moment the deposit is actually created. If the surface is already dull in patches rather than filmed, that is etching rather than scale, no cleaning method will touch it, and re-polishing is a job for a stone restorer.

    Sources for this page

    Sources

    1. Care & Cleaning of Natural Stone

      Natural Stone Institute · Trade or professional body

      Relied on for: That calcareous stone consists primarily of calcium carbonate and is sensitive to acidic solutions, that lemon and vinegar dull or etch it, and that etching is distinct from staining. (states this directly)

      Verification: a person has read the passage relied on.

      Read on Sprint 29 read all nine sections. Earlier sprints had read three: the siliceous-versus-calcareous classification, cleaning products, and sealing. Supports a wider statement — our claim was widened. Three sections of nine had been read and the source treated as complete. The unread six carry the whole preventive programme - coasters, trivets, non-treated dry mopping, slip-resistant mats, worn vacuum wheels, blot-don't-wipe - none of which the register held. They also answer a priority-1 row reading 'no route answers this yet': the authority's position on etch marks is that they are not a cleaning problem and need professional re-polishing. Two oddities are worth the record: dry 0000 steel wool is permitted on water rings, and efflorescence is removed dry because water makes it worse.

    2. Kirk-Othmer Encyclopedia of Chemical Technology

      John Wiley & Sons · Reference work

      Relied on for: That acids react with carbonates to form soluble salts and carbon dioxide. (background and mechanism only)

      Verification: the work exists and is described correctly. Nobody has yet read the specific passage.

    What CleaningHQ cannot answer yet

    These are recorded questions about this subject that we have not yet researched to a standard we would publish.

    • Repair acid etching on polished marble
    • Compare maintenance requirements of stone types
    • Resealing frequency for natural stone
    • Identify a worktop material before cleaning it
    • Find a cleaner compatible with two sensitive surfaces

    Last reviewed by a person on .

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